一、个人简介
刘清泉,1974年出生,湖南隆回人,教授、博导,湖南省电池协会理事、专家委员会委员,广东省科技特派员。现任凯发旗舰厅官网院长,兼任新能源储存与转换先进材料湖南省重点实验室主任。主要研究方向为微孔有机高分子材料的设计、合成及在环境净化和清洁能源中的应用;水性乳液制备关键技术与工艺研究。先后主持国家自然科学基金3项、湖南省高新技术产业科技创新引领计划等省部级项目4项、企业委托项目5项;主持建设“新能源储存与转换先进材料“湖南省重点实验室;主持获得湖南省自然科学二等奖1项、湖南省高等教育教学成果三等奖1项,作为主要完成人,获湖南省科技进步奖二等奖1项(3) 、东莞市科技进步二等奖1项(2)、东莞市专利优秀奖1项(2);在《J Mater Chem A》《Sep Purif Technol》《Acs Appl Mater Interfaces》等学术期刊上发表论文60余篇;获授权国家发明专利12项,应用与转化专利5项。
联系方式:qqliu@hnust.edu.cn
二、学习经历
2006/09–2009/09 浙江大学化学工程国家重点实验室,高分子化学与物理专业,博士
2000/09–2003/06 中南大学化学化工学院,应用化学专业,硕士
1993/09–1996/06 湖南工程学院化学系,工业分析专业,大专
三、工作经历
2016/06–至今 湖南科技大学凯发旗舰厅官网
2014/09–2015/09 新加坡国立大学生物与分子工程系,访问学者
2003/06–2016/06 湖南科技大学化学化工学院
1996/08–2000/08 湖南宝庆化工厂
四、研究方向
1. 多孔高分子材料的设计、合成及在光催化、气体存储与分离中的应用;
2. 多孔高分子材料的设计、合成及其在金属离子回收与废水处理中的应用;
3. 水性润滑剂和水性蜡乳液制备的关键技术与工艺研究。
五、奖励与荣誉
[1] 周智华, 张少伟, 郑柏树, 赵云辉, 方建军, 刘清泉, 刘立华. “四协四融”培养地方高校化材类创新人才探索与实践. 湖南省高等教育教学成果三等奖, 2022年.
[2] 刘清泉, 刘欢, 廖博, 周智华, 欧宝立. 基于染料和CO2吸附多孔聚合物杂化材料的构建. 湖南省自然科学奖二等奖, 2020年.
[3] 刘清泉, 田俐, 陈丽娟, 欧宝立, 彭美勋. 实施“12345”工程培养材料化学专业复合型人才. 湖南省高等教育教学成果三等奖, 2019年.
[4] 周虎, 周智华, 刘清泉. PCB微钻孔用吸热与润滑型覆膜铝基盖板材料的制备技术及应用. 湖南省科技进步奖二等奖, 2015年.
[5] 荀育军, 刘清泉. 环保型水性化硬脂酸盐系列产品的开发及产业化. 东莞市科技进步二等奖, 2013年.
[6] 荀育军, 刘清泉. 一种水性硬脂酸锌分散液及其制备方法. 东莞市专利优秀奖. 2012年.
[7] 刘清泉. 湘潭市C类高端人才, 2019年.
六、研究项目与平台建设
[1] 新能源储存与转换先进材料湖南省重点实验室(2018TP1037), 湖南省重点实验室, 201807~202106.
[2] 磁性共轭微孔聚合物的设计、合成与优化及在铟回收中的应用(51778226), 国家自然科学基金, 201801~202112.
[3] 有序纳米孔道交联聚苯乙烯整体材料设计合成与优化(51373051), 国家自然科学基金, 201401~201712.
[4] 软模板法制备有序多孔的交联聚苯乙烯材料(21044004), 国家自然科学基金, 201101~201112.
[5] 汽车用水性阻尼涂料的关键技术研究(2020GK2054), 湖南省创新引领计划, 202007~202212.
[6] 沥青转化磁性超交联聚合物及其对低浓度稀土 离子的吸附特性研究(2023JJ30250),湖南省自然科学基金,202301-202512.
[7] 系列水性高密度氧化聚乙烯蜡微乳液制备关键技术研究(2020430304000310), 横向项目, 202007~202112.
[8] 系列水性高密度氧化聚乙烯蜡微乳液制备关键技术研究, 广东省企业特派员专项,202007~202112.
[9] 水性润滑剂的研究与产业化(2019430304000082), 横向项目, 201906~202106.
[10] 氧化聚乙烯蜡微乳液的产业化研究(201543030 4000118), 横向项目, 201507~ 201512.
[11] 一种以单一乳化剂制备非离子型氧化聚乙烯蜡乳液的方法(2014430304000078), 专利转让, 201405~201412.
[12] 有序纳米孔道交联聚苯乙烯整体材料设计合成与优化(14JJ2095), 湖南省自然科学基金, 201401~201612.
[13] 孔排列高度有序的交联聚苯乙烯材料的研究(2011M501285), 中国博士后面上项目, 201107~ 201206.
[14] 多孔磁性聚苯乙烯微球的制备及在印染废水处理中的应用研究(2011051226), 中南大学博士后基金, 201107~ 201206.
[15] 硬脂酸钙乳液的产业化(2010430304000025), 横向项目, 201012~201106.
七、研究成果论文
[1] Zhang WJ, Sun PH, Wang BX, Li ST , Yi B , Liu QQ*, Yang H*. Polarization engineering of conjugated microporous polymers to boost exciton dissociation by dielectric constant regulation for photocatalytic degradation of antibiotics. Sep. Purif. Technol. 2024, 332: 125776
[2] Xiong SH*, Huang HW, Tang TZ, Cao XX, Zhao HW, Li G, Liu H, Zhang WJ, Liu QQ*. Creating high-afffnity binding sites for efffcient CO2 and iodine vapor uptake through direct synthesis of novel triazine-based covalent organic polymers. J. Mater. Res. Technol. 2023, 27: 5629-5638.
[3] Zhang B, Song DZ, Liu YZ, Deng QX, Yuan Y, Liu QQ*, Hou J*. Porosity engineering of biochar-based single-atom Ni catalysts to promote CO2 electroreduction over a broad potential window. AICHE J. 2023; e18175.
[4] Wei SX, Lu W,* Shi HH, Wu SS, Le XX, Yin GQ, Liu QQ, Chen T. Light-writing and projecting multicolor fluorescent hydrogels for on-demand information display. Adv. Mater. 2023, 2300615.
[5] Wu CW, Li F, Zeng YJ, Zhao HW, Xie GF, Zhou WX* , Liu QQ*, Zhang G*. Machine learning accelerated design of 2D covalent organic frame materials for thermoelectrics. Appl. Surf. Sci. 2023, 638: 157947.
[6] Zhang C, Xiao P, Zhang D, Ni F, Gu JC, Liu QQ, Kuo SW, Chen T. Wet-spinning knittable hygroscopic organogel fibers toward moisture-capture-enabled multifunctional devices. Adv. Fiber Mater. 2023, 5: 588-602.
[7] Peng Q, Zhao HW*, Yang QL, Chen G, Cao XX, Xiong SH, Xiao AG*, Li G, Liu B, Liu QQ*. Investigation of hydrogen adsorption sites in ferrocene-based hypercrosslinked polymers by DFT calculations. J. Mater. Res. Technol. 2023, 24: 7189-7197.
[8] Peng Q, Zhao HW*, Chen G, Yang QL, Cao XX, Xiong SH, Xiao AG*, Li G, Liu B, Liu QQ*. Synthesis of novel magnetic pitch-based hypercrosslinked polymers as adsorbents for effective recovery of Ag+ with high selectivity. J. Environ. Manage. 2023, 339, 117763.
[9] Zhang WJ, Deng ZZ, Deng JY, Au C, Liao YF, Yang H*, Liu QQ*. Regulating the exciton binding energy of covalent triazine frameworks for enhancing photocatalysis. J. Mater. Chem. A 2022, 10, 22419–22427. Journal of Materials Chemistry A HOT Papers
[10] Sun PH, Wang PG, Yan D, Liu Q, Zhang WJ*, Deng JY*, Liu QQ*. Boosting charge separation in conjugated microporous polymers via fluorination for enhancing photocatalysis. Catal. Sci. Technol. 2022, 12, 5942–5951.
[11] Deng ZZ, Zhao HW, Cao XX, Xiong SH, Li G, Deng JY, Yang H, Zhang WJ*, Liu QQ*. Enhancing built-in electric field via molecular dipole control in conjugated microporous polymers for boosting charge separation. ACS Appl. Mater. Interfaces 2022, 14, 35745– 35754.
[12] Lu HH, Wu BY*, Le XX, Lu W, Yang Q, Liu QQ, Zhang JW*, Chen T*. Programming shape memory hydrogel to a pre-encoded static deformation toward hierarchical morphological information encryption. Adv. Funct. Mater. 2022, 2206912.
[13] Shang H, Le XX*, Sun Y, Shan FQ, Wu SS, Zheng YF, Li DY, Guo D, Liu QQ, Chen T*. Integrating photo-rewritable fluorescent information in shape-memory organohydrogel towards dual encryption. Adv. Opt. Mater. 2022, 202200608.
[14] Yuan Y, Liu YZ, Li CH, Feng S, Liu QQ*, Huo J*. Hierarchically porous N-doped carbon nanosheet networks with ultrafine encapsulated Fe3C and Fe-Nx for oxygen reduction reaction in alkaline and acidic media. J. Alloy Compd. 2022, 920: 165821.
[15] Wang RY, Liu QQ*, Peng Q, Yang XY, Zhao HW, Fan H, Liu H, Cao XX*. A novel strategy to improve gas capture performance of metal-free azo-bridged porphyrin porous organic polymers: The design of traps. Eur. Polym. J. 2022, 175: 111359.
[16] Gu J, Xiao P*, Guan JM, Ni F, Zhang C, Yang WQ, Liu QQ, Chen T*. Coral-like hierarchically nanostructured membrane with high free volume for salt-free solar-enabled water purification. Mater. Today Phys. 2022, 25: 100715.
[17] Zhang B, Tan ZQ, Zhang YH, Liu QQ*, Li QX, Li G*. Facile synthesis of microporous ferrocenyl polymers photocatalyst for degradation of cationic dye. Polymers, 2022, 14, 1900.
[18] Yang WQ, Xiao X*, Ni F, Zhang C, Gu JC, Kuo SW, Liu QQ, Chen T*. Biomass-derived nanostructured coatings based on cellulose nanofibers-melanin hybrids toward solar-enabled multifunctional energy management. Nano Energy 2022, 97: 107180.
[19] Peng Q, Zhao HW*, Wang RY, Cao XX, Liu H, Liu QQ*. Ferrocene-based hypercrosslinked polymers derived from phenolic polycondensation with unexpected H2 adsorption capacity. Mater. Today Chem. 2022, 24: 100854.
[20] Liu YZ, Li CH, Loubidi M, Wang DD, Zhou L, Niu SY, Liu QQ, Huo J*. Increasing exposure of atomically dispersed Ni sites via constructing hierarchically porous supports for enhanced electrochemical CO2 reduction. Chem. Eng. J. 2021, 426: 131414.
[21] Zhang WJ, Peng Q, Yang H, Fang ZJ, Deng JY, Yu GP*, Liao YF, Liu QQ*. Modulating carrier transfer over carbazolic conjugated microporous polymers via donor structural design for functionalization of thiophenols. ACS Appl. Mater. Interfaces 2021, 13, 60072−60083.
[22] Zhang WJ, Deng JY, Fang ZJ, Lan DH, Liao YF, Zhou X, Liu QQ*. Promoting charge separation in donor-acceptor conjugated microporous polymers via cyanidation for photocatalytic reductive dehalogenation of chlorides. Catal. Sci. Technol. 2021, 11, 7151–7159.
[23] Cao XX, Wang RY, Peng Q, Zhao HW, Fan H, Liu H*, Liu QQ*. Effect of pore structure on the adsorption capacities to different sizes of adsorbates by ferrocene-based conjugated microporous polymers. Polymer, 2021, 233: 123194.
[24] Li QL, Liu YB, Niu SY, Li CH, Chen C, Liu QQ*, Huo J*. Microwave-assisted rapid synthesis and activation of ultrathintrimetal–organic framework nanosheets for efficient electrocatalyticoxygen evolution. J. Colloid Interf. Sci. 2021, 603: 148–156.
[25] Liu CH, Xia JY, Gu JC*, Wang WQ, Liu QQ, Yan LK, Chen T*. Multifunctional CNTs-PAA/MIL101(Fe)@Pt composite membrane for high- throughput oily wastewater remediation. J. Hazard. Mater. 2021, 403: 123547.
[26] Zhan BB, Wei SX, Hu ZF, Liu H, Qiu HY, Liu QQ*, Lu W*, Chen T*. Multicolor fluorescent polymeric actuator with self-sustained oscillation behavior. Macromol. Mater. Eng. 2021, 2000781.
[27] Zhang C, Peng X, Feng N, Yan LK, Liu QQ, Zhang D, Gu JC, Wang WQ, Chen T*. Converting pomelo peel into eco-friendly and low-consumption photothermic biomass sponge toward multifunctioal solar-to-heat conversion. ACS Sustain. Chem. Eng. 2020, 8: 5328- 5337.
[28] Tan ZQ, Su HM, Guo YW, Liu H, Liao B, Amin AM, Liu QQ*. Ferrocene-based conjugated microporous polymers derived from Yamamoto coupling for gas storage and dye removal. Polymers, 2020, 12: 719–730.
[29] Huang J, Tan ZQ, Su HM, Guo YW, Liu H, Liao B, Liu QQ*. Ferrocenyl building block constructing porous organic polymer for gas capture and methyl violet adsorption. J Centr. South Univ. 2020, 22:1247–1261.
[30] Xiong SH, Tao J, Wang YY, Tang JT, Liu C, Liu QQ, Wang Y, Yu GP*, Pan CY. Uniform poly(phosphazene–triazine) porous microspheres for highly efficient iodine removal. Chem. Commun. 2018, 54, 450–8453
[31] 夏碧江, 方嘉伟, 黎姗, 唐乃卓, 刘清泉*. 卟啉基多孔有机聚合物的合成、表征及其气体吸附性能研究. 材料导报, 2018, 32: 144–148.
[32] Li G, Liu QQ*, Liao B, Chen LJ, Zhou H, Zhou ZH, Xia BJ, Huang J, Liu B. Synthesis of novel ferrocene-based conjugated microporous polymers with intrinsic magnetism. Eur. Polym. J. 2017, 93: 556–560.
[33] Li G, Liu QQ*, Xia BJ, Huang J, Li SZ, Guang YZ, Zhou H, Liao B, Zhou ZH, Liu B. Synthesis of stable metal-containing porous organic polymers for gas storage. Eur. Polym. J. 2017, 91: 242–247.
[34] Xiao HX*, Zhou ZH, Zhou H, Liu QQ*, Ren WX, Lin HL, Zhu HP, He C, Tian K. Conversion of HBr to Br2 in the flue gas from the combustion of waste printed circuit boards in post-combustion area. J. Clean. Prod. 2017, 161: 239–244
[35] Liu QQ*, Xia BJ, Huang J, Liao B, Liu H, Ou BL, Chen LJ, Zhou ZH. Hypercrosslinked polystyrene microspheres with ultrahigh surface area and their application in gas storage. Mater. Chem. Phys. 2017, 199: 616–622.
[36] Liu QQ*, Li G, Tang Z, Chen LJ, Liao B, Ou BL, Zhou ZH, Zhou H. Design and synthesis conjugated microporous polymers with different pore-size distribution and tunable surface area. Mater. Chem. Phys. 2017, 186: 11–18.
[37] Liu QQ*, Tang Z, Wu MD, Liao B, Zhou H, Ou BL, Yu GP, Zhou ZH, Li XJ. Novel ferrocene-based nanoporous organic polymers for clean energy application. RSC Adv. 2015, 5: 8933–8977.
[38] Liu QQ*, Wu MD, Duan YX, Ou BL, Liao B, Shen SH, and Zhou H. Functional Block Copolymers from Controlled Radical and Ring Opening Polymerization. Polym. Sci. B. 2015, 57: 387-394.
[39] Liu QQ*, Tang Z, Wu MD, Zhou ZH. Design, preparation and application of conjugated microporous polymers. Polym. Int. 2014, 63: 381–392.
[40] Liu QQ*, Tang Z, Zhou ZH, Zhou H, Ou BL, Liao B, Shen SH, Chen LJ. A novel route to prepare cationic polystyrene latex particles with monodispersity. J. Macromol. Sci. A 2014, 51: 271–278.
[41] Liu QQ*, Tang Z, Ou BL, Liu LH, Zhou ZH, Shen SH, Duan YX. Design, preparation, and application of ordered porous polymer materials. Mater. Chem. Phys. 2014, 144: 213–225.
[42] 刘清泉, 潘春跃, 申少华, 王鸣玉, 王娟, 张鹏鹏. 新型共致孔剂对多孔聚二乙烯基苯微球孔结构的影响研究. 湖南科技大学学报( 自然科学版) 2013, 28: 102–106.
[43] Liu QQ*, Duan YX, Shen SH, Zhou ZH. The influence of different porogens with halogen substituents on the pore structure of polydivinylbenzene beads. Mater. Chem. Phys. 2012, 134: 122–126.
[44] Liu QQ*, Li YL, Duan YX, Zhou ZH. Research progress on the preparation and application of monodisperse cationic polymer latex particles. Polym. Int. 2012, 61: 1593–1602.
[45] Liu QQ*, Pan CY. A novel route to treat wastewater containing cationic dyes. Sep. Sci. Technol. 2012, 47: 630–635.
[46] 刘清泉, 周仕祥, 杨震, 瞿作明, 杨萍, 周建华, 高敬民. 以单一非离子型乳化剂制备氧化聚乙烯蜡微乳液. 涂料工业 2012, 42:43–45.
[47] Liu QQ*, Li YL, Shen SH, Zhou SS. The influence of crosslinking density on the pore morphology of copolymer beads prepared with a novel pore-forming agent. Mater. Chem. Phys. 2011, 125: 315–318.
[48] Liu QQ*, Duan YX, Shen SH, Zhou ZH. A simple route to prepare pomegranate-like polystyrene-basedmicrospheres with high porosity. Polym. Int. 2011, 60: 1287–1290.
[49] Liu QQ*, Li YL, Shen SH, Xiao QG, Chen LJ, Liao B, Ou BL, Ding Y. Preparation and characterization of crosslinked polymer beads with tunable pore morphology. J. Appl. Polym. Sci. 2011, 121: 654–659.
[50] Liu QQ*. Monodisperse polystyrene nanospheres with ultra-high surface area and their application in hydrogen storage. Macromol. Chem. Phys. 2010, 211: 1012–1017.
[51] Liu QQ*, Li YL, Shen SH, Zhou ZH, Ou BL, Tang SL. Preparation of monodisperse cationic microspheres by dispersion polymerization of styrene and a cation-charged monomer in the absence of a stabilizer. J. Macromol. Sci. A 2011, 48: 518–525.
[52] Liu QQ, Wang L*, Xiao AG, Gao JM, Ding WB, Yu HJJHJHJHKEIR JDFSKJ, Huo J, Ericson M. Templated preparation of porous magnetic microspheres and their application in removal of cationic dyes from wastewater. J. Hazard. Mater. 2010, 181: 586–592.
[53] Liu QQ, Wang L*, Yu WT, Xiao AG, Yu HJ, Huo J. Hyper-cross-linked polystyrene microspheres with bimodal pore size distribution and controllable macroporosity. J. Appl. Polym. Sci. 2010, 116: 84–92.
[54] Liu QQ, Wang L*, Yu WT, Xiao AG, Gao JM, Ding WB, Yu HJ. Research on cleavage behavior and mechanism of poly(divinylbenzene) microspheres. Des. Monomers Polym. 2010, 13: 369–375.
[55] Liu QQ, Wang L*, Xiao AG, Yu HJ, Ericson M. Regeneration of porous magnetic microspheres during treatment wastewater containing cationic dyes. Sep. Sci. Technol. 2010, 45: 2345–2349.
[56] Liu QQ, Wang L*, Xiao AG, Yu HJ, Ding JH, Tan QH, Huo J. Preparation of poly(divinylbenzene) microspheres with controllable pore structure using poly(propylene)/toluene as coporogen. J. Appl. Polym. Sci. 2009, 113:2997–3004.
[57] Liu QQ*, Shen SH, Zhou ZH, Tan L. A facile route to synthesis of superparamagnetic Fe3O4-PDVB nanoworms. Mater. Lett. 2009, 63: 2625–2627.
[58] Liu QQ, Wang L*, Xiao AG, Yu HJ, Tan QH, Ding JH,Ren GQ. Unexpected behavior of 1-chlorodecane as a novel porogen in the preparation of high-porosity poly(divinyl- benzene) microspheres. J. Phys. Chem. C 2008, 112: 13171–13174.
[59] Liu QQ, Wang L*, Xiao AG, Yu HJ, Tan QH. A hyper-cross-linked polystyrene with nano-pore structure. Eur. Polym. J. 2008, 44: 2516–2522.
八、国家发明专利
[1] 刘清泉,张兵,彭琪,王瑞元,赵宏伟,曹新秀,刘欢。一种以减压渣油制备磁性超交联聚合物的方法,发明专利: ZL202110966682.1, 2023年授权.
[2] 刘清泉, 李根. 一种酰胺键接的二茂铁铁纳米多孔聚合物的制备方法, 发明专利: ZL201510949 179.X, 2018年授权.
[3] 刘清泉, 李根. 一种二茂铁基共轭微孔聚合物的制备方法. 发明专利: ZL201510949189.3, 2017年授权.
[4] 刘清泉, 李根, 周虎, 周智华, 关钰泽, 罗春萍, 张圳. 磁性微孔二茂铁桥联聚咔唑的制备方法, 专利号: ZL201610197977.6, 2017年授权.
[5] 刘清泉, 唐哲, 廖博. 一种制备单分散阳离子型聚苯乙烯微球的简单方法,发明专利: ZL2013 10113898.9,2016年授权. 已转让
[6] 刘清泉, 唐哲, 廖博, 龙鵬. 一种制备单分散阴离子型聚苯乙烯微球的简单方法. 发明专利: ZL2013 10083739.9,2015年授权. 已转让
[7] 刘清泉, 唐哲, 廖博, 龙鵬. 一种超高比表面积单分散聚合物微球的制备方法. 发明专利: ZL20131 0113977.X,2015年授权. 已转让
[8] 刘清泉, 唐哲, 廖博. 一种蠕虫状超顺磁性纳米复合材料的制备方法. 发明专利: ZL20131008 4241.4,2014年授权.
[9] 刘清泉. 一种单分散大尺寸碳球的制备方法. 发明专利: ZL201110327415.6,2013年授权.
[10] 刘清泉, 李艳禄. 一种粒径可控的单分散阳离子型聚苯乙烯微球的制备方法. 发明专利: ZL201110 327414.1, 2013年授权.
[11] 刘清泉, 周仕祥, 杨萍, 瞿作明. 一种以单一乳化剂制备离子型氧化聚乙烯蜡乳液的方法. 发明专利: ZL201110076881.1,2012年授权.
[12] 刘清泉, 周仕祥, 杨萍, 瞿作明. 一种以单一乳化剂制备非离子型氧化聚乙烯蜡乳液的方法. 发明专利: ZL201110076883.0,2012年授权. 已转让
[13] 荀育军, 刘清泉. 一种水性硬脂酸锌分散液及其制备方法. 发明专利: ZL201010552926.3,2012年授权, 已应用.
九、育人成效
[1] 指导4名2022届本科毕业生中,2人考取国内知名高校研究生,2人签约就业,就业率100%。
[2] 指导6名2021届本科毕业生中,4人考取国内知名高校研究生,1人签约就业。
[3] 指导5名2022届本科毕业生中,3人考取国内知名高校研究生,1人签约就业。
[4] 苏惠敏, 黎姗, 郭翼雯. 第十六届“挑战杯”全国大学生课外学术科技作品竞赛三等奖, 2019年.
[5] 苏惠敏, 黎姗, 郭翼雯. 第十三届“挑战杯”湖南省大学生课外学术科技作品竞赛二等奖, 2019年.
[6] 方嘉炜, 黎姗, 唐乃卓. 湖南省第八届大学生化学化工实验与创新设计竞赛(课外化工类创新作品) 二等奖, 2018年.
[7] 方嘉炜, 黎姗, 唐乃卓. 第十届湖南省大学生课外化学化工创新作品竞赛特等奖, 2018年.
[8] 李晓娟, 罗春萍, 罗春萍, 李思哲. 国家级大学生创新创业训练计划项目, 2015-2016年.
[9] 关钰泽, 李思哲, 张震. 湖南科技大学SRIP“挑战杯专项”项目, 2016-2017年.